Micro and nanocomposites of polybutadienebased polyurethane liners with mineral fillers and nanoclay: thermal and mechanical properties
Abstract: Micro and nanocomposites of hydroxyl terminated polybutadiene (HTPB)-based polyurethanes (NPU) were obtained using five mineral fillers and Cloisite 20A nanoclay, respectively. Samples were prepared by the reaction of HTPB polyol and toluene diisocyanate (TDI), and the chain was further extended with glyceryl monoricinoleate to produce the final elastomeric polyurethanes. Mechanical and thermal properties were studied, showing that mineral fillers (20%w/w) significantly increased tensile strength, in particular nanoclay (at 5% w/w). When nanoclay-polymer dispersion was modified with a silane and hydantoin-bond promoter, elongation at break was significantly increased with respect to NPU with C20A. Thermal properties measured by differential scanning calorimetry (DSC) were not significantly affected in any case. The molecular structure of prepared micro and nanocomposites was confirmed by Fourier transform infrared (FTIR) spectroscopy and Raman spectroscopy. Interaction of fillers with polymer chains is discussed, considering the role of silanes in compatibilization of hydrophilic mineral fillers and hydrophobic polymer. The functionalization of nanoclay with HMDS silane was confirmed using FTIR. Microstructure of NPU with C20A nanoclay was confirmed by Atomic Force Microscopy (AFM).
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Micro and nanocomposites of polybutadienebased polyurethane liners with mineral fillers and nanoclay: thermal and mechanical properties ; volume:15 ; number:1 ; year:2017 ; pages:46-52 ; extent:7
Open chemistry ; 15, Heft 1 (2017), 46-52 (gesamt 7)
- Creator
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Ross, Pablo
Escobar, Germán
Sevilla, Guillermo
Quagliano, Javier
- DOI
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10.1515/chem-2017-0006
- URN
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urn:nbn:de:101:1-2410161554366.324496366757
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:37 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Ross, Pablo
- Escobar, Germán
- Sevilla, Guillermo
- Quagliano, Javier
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