Molecular Structure Effects on Ionic Diode Performance in Desalination: Ultrahigh Rectification in Butylated Intrinsically Microporous Polyamine (PIM‐EA‐TB)
Abstract: Ionic diodes are components in ionic circuits for AC‐electricity driven desalination and ion extraction processes. Independent of the ionic diode type/mechanism, achieving ionic current rectification at high ionic strengths is challenging but important, for example in seawater desalination and treatment of brine. Here, the butylation of a molecularly rigid (glassy) polymer of intrinsic microporosity (PIM‐EA‐TB) is shown to give anionic diodes with ultrahigh rectification effects (associated with interfacial resistivity) even in high ionic strength aqueous 2 M NaCl solution. The effect is rationalised based on polymer structure affecting ion transport.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Molecular Structure Effects on Ionic Diode Performance in Desalination: Ultrahigh Rectification in Butylated Intrinsically Microporous Polyamine (PIM‐EA‐TB) ; day:07 ; month:03 ; year:2024 ; extent:9
ChemElectroChem ; (07.03.2024) (gesamt 9)
- Urheber
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Li, Zhongkai
Carta, Mariolino
McKeown, Neil B.
Agbenyeke, Raphael E.
Eloi, Jean‐Charles
Fermin, David
Arotiba, Omotayo A.
Marken, Frank
- DOI
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10.1002/celc.202300807
- URN
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urn:nbn:de:101:1-2024030813285333400168
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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14.08.2025, 10:54 MESZ
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Beteiligte
- Li, Zhongkai
- Carta, Mariolino
- McKeown, Neil B.
- Agbenyeke, Raphael E.
- Eloi, Jean‐Charles
- Fermin, David
- Arotiba, Omotayo A.
- Marken, Frank
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The immobilisation and reactivity of Fe(CN)6 3−/4− in an intrinsically microporous polyamine (PIM-EA-TB)
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Rectification.
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The immobilisation and reactivity of Fe(CN)6 3−/4− in an intrinsically microporous polyamine (PIM-EA-TB)
Ionic Diode and Molecular Pump Phenomena Associated with Caffeic Acid Accumulated into an Intrinsically Microporous Polyamine (PIM‐EA‐TB)
Hydrogen Peroxide Versus Hydrogen Generation at Bipolar Pd/Au Nano-catalysts Grown into an Intrinsically Microporous Polyamine (PIM-EA-TB)
Intrinsically Microporous Polymer Nanosheets for High‐Performance Gas Separation Membranes
Size‐Selective Photoelectrochemical Reactions in Microporous Environments: Clark Probe Investigation of Ptg‐C 3 N 4 Embedded into Intrinsically Microporous Polymer (PIM‐1)
Intrinsically microporous polyimide-based metal-free catalysts for round-the-clock photodegradation of organic pollutants
PolyMOF nanoparticles constructed from intrinsically microporous polymer ligand towards scalable composite membranes for CO2 separation
Rectification.
Rectification.
Rectification.
Rectification.