The Oxidation of Organo‐Boron Compounds Using Electrochemically Generated Peroxodicarbonate

Abstract: Peroxodicarbonate represents a green and largely underexplored oxidizer generated electrochemically from aqueous carbonate solutions. Through state‐of‐the‐art electrolyzer technology, highly concentrated solutions have now become accessible. These were successfully employed as green oxidizer in deborolative hydroxylations. A plethora of phenols and alcohols have thus been synthesized in up to 99 % from organoboron compounds using only green and non‐toxic solvents. This transformation was successfully scaled‐up to multi‐gram batch sizes.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
The Oxidation of Organo‐Boron Compounds Using Electrochemically Generated Peroxodicarbonate ; day:12 ; month:04 ; year:2023 ; extent:7
European journal of organic chemistry ; (12.04.2023) (gesamt 7)

Creator
Kohlpaintner, Philipp J.
Marquart, Lucas
Gooßen, Lukas J.
Waldvogel, Siegfried R.

DOI
10.1002/ejoc.202300220
URN
urn:nbn:de:101:1-2023041215083416053516
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 10:54 AM CEST

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