Stereoselective Synthesis of Mechanically Planar Chiral Rotaxanes
Abstract: Chiral interlocked molecules in which the mechanical bond provides the sole stereogenic unit are typically produced with no control over the mechanical stereochemistry. Here we report a stereoselective approach to mechanically planar chiral rotaxanes in up to 98:2 d.r. using a readily available α‐amino acid‐derived azide. Symmetrization of the covalent stereocenter yields a rotaxane in which the mechanical bond provides the only stereogenic element.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Stereoselective Synthesis of Mechanically Planar Chiral Rotaxanes ; volume:57 ; number:45 ; year:2018 ; pages:14806-14810 ; extent:5
Angewandte Chemie / International edition. International edition ; 57, Heft 45 (2018), 14806-14810 (gesamt 5)
- Creator
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Jinks, Michael A.
de Juan, Alberto
Denis, Mathieu
Fletcher, Catherine J.
Galli, Marzia
Jamieson, Ellen M. G.
Modicom, Florian
Zhang, Zhihui
Goldup, Stephen M.
- DOI
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10.1002/anie.201808990
- URN
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urn:nbn:de:101:1-2022081605515450118052
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:36 AM CEST
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Associated
- Jinks, Michael A.
- de Juan, Alberto
- Denis, Mathieu
- Fletcher, Catherine J.
- Galli, Marzia
- Jamieson, Ellen M. G.
- Modicom, Florian
- Zhang, Zhihui
- Goldup, Stephen M.
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