Comparison of Iridium (I) Catalysts in Temperature Mediated Hydrogen Isotope Exchange Reactions

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Abstract: The reactivity and selectivity of iridium (I) catalysed hydrogen isotope exchange (HIE) reactions can be varied by using wide range of reaction temperatures. Herein, we have done a detailed comparison study with common iridium (I) catalysts (1–6) which will help us to understand and optimize the approaches of either high selectivity or maximum deuterium incorporation. We have demonstrated that the temperature window for these studied iridium (I) catalysts is surprisingly very broad. This principle was further proven in some HIE reactions on complex drug molecules.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Comparison of Iridium (I) Catalysts in Temperature Mediated Hydrogen Isotope Exchange Reactions ; volume:8 ; number:9 ; year:2019 ; pages:1183-1189 ; extent:7
ChemistryOpen ; 8, Heft 9 (2019), 1183-1189 (gesamt 7)

Urheber
Valero, Mégane
Mishra, Anurag
Blass, Jennifer
Weck, Remo
Derdau, Volker

DOI
10.1002/open.201900204
URN
urn:nbn:de:101:1-2022073007222119510931
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:37 MESZ

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Beteiligte

  • Valero, Mégane
  • Mishra, Anurag
  • Blass, Jennifer
  • Weck, Remo
  • Derdau, Volker

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