Furan Synthesis via Triplet Sensitization of Acceptor/Acceptor Diazoalkanes
Abstract: Herein, we report on the photocatalytic reaction of acceptor/acceptor diazoalkanes with terminal alkynes. Experimental and computational studies suggest the formation of a key triplet carbene intermediate that undergoes an addition reaction to the alkyne followed by cyclization to give furan heterocycles (31 to 90% yield). This reaction was studied with a broad range of alkynes and acceptor/acceptor diazoalkanes and now provides access to furans under mild reaction conditions.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Furan Synthesis via Triplet Sensitization of Acceptor/Acceptor Diazoalkanes ; day:24 ; month:08 ; year:2022 ; extent:1
Advanced synthesis & catalysis ; (24.08.2022) (gesamt 1)
- Urheber
- DOI
-
10.1002/adsc.202200654
- URN
-
urn:nbn:de:101:1-2022082415352408118320
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 15.08.2025, 07:37 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Zhu, Siqi
- Li, Fang
- Empel, Claire
- Jana, Sripati
- Pei, Chao
- Koenigs, Rene M.
Ähnliche Objekte (12)
Furan Synthesis via Triplet Sensitization of Acceptor/Acceptor Diazoalkanes
Donor acceptor substituted triplet emitters
EPR of photoexcited triplet-state acceptor porphyrins
Anforderungsermittlung an ein Beschreibungsmittel und Erweiterung einer Gerätebeschreibungssprache für die modulare Automatisierung im Maschinen- und Anlagenbau
“Are you there?”: Teaching presence and interaction in large online literature classes
Association Between the Risk of Dental Caries and DLX3 Gene Polymorphisms in Chinese Children
Triplet–Triplet Annihilation Upconversion in a MOF with AcceptorFilled Channels
Triplet‐Forming Thionated Donor‐Acceptor Chromophores for Electrochemically Amphoteric Photosensitization
Environmental Control of Triplet Emission in Donor–Bridge–Acceptor Organometallics
Understanding the Role of Triplet‐Triplet Annihilation in Non‐Fullerene Acceptor Organic Solar Cells
Intramolekulare Donor-Acceptor-Systeme mit Tetracyanobenzol als Acceptor
Existence and attractivity of global solutions for a class of fractional quadratic integral equations in Banach space
Furan Synthesis via Triplet Sensitization of Acceptor/Acceptor Diazoalkanes
Donor acceptor substituted triplet emitters
EPR of photoexcited triplet-state acceptor porphyrins
Anforderungsermittlung an ein Beschreibungsmittel und Erweiterung einer Gerätebeschreibungssprache für die modulare Automatisierung im Maschinen- und Anlagenbau
“Are you there?”: Teaching presence and interaction in large online literature classes
Association Between the Risk of Dental Caries and DLX3 Gene Polymorphisms in Chinese Children
Triplet–Triplet Annihilation Upconversion in a MOF with AcceptorFilled Channels
Triplet‐Forming Thionated Donor‐Acceptor Chromophores for Electrochemically Amphoteric Photosensitization
Environmental Control of Triplet Emission in Donor–Bridge–Acceptor Organometallics
Understanding the Role of Triplet‐Triplet Annihilation in Non‐Fullerene Acceptor Organic Solar Cells
Intramolekulare Donor-Acceptor-Systeme mit Tetracyanobenzol als Acceptor
Existence and attractivity of global solutions for a class of fractional quadratic integral equations in Banach space
Furan Synthesis via Triplet Sensitization of Acceptor/Acceptor Diazoalkanes
Donor acceptor substituted triplet emitters
EPR of photoexcited triplet-state acceptor porphyrins
Anforderungsermittlung an ein Beschreibungsmittel und Erweiterung einer Gerätebeschreibungssprache für die modulare Automatisierung im Maschinen- und Anlagenbau
“Are you there?”: Teaching presence and interaction in large online literature classes
Association Between the Risk of Dental Caries and DLX3 Gene Polymorphisms in Chinese Children
Triplet–Triplet Annihilation Upconversion in a MOF with AcceptorFilled Channels
Triplet‐Forming Thionated Donor‐Acceptor Chromophores for Electrochemically Amphoteric Photosensitization
Environmental Control of Triplet Emission in Donor–Bridge–Acceptor Organometallics
Understanding the Role of Triplet‐Triplet Annihilation in Non‐Fullerene Acceptor Organic Solar Cells
Intramolekulare Donor-Acceptor-Systeme mit Tetracyanobenzol als Acceptor