Dinuclear Gold (I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands
Abstract: A novel N,N’‐allyl‐bridged bisimidazolium salt and a novel dinuclear Ag (I) and a Au (I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl‐group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd (II).
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Dinuclear Gold (I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands ; volume:15 ; number:12 ; year:2020 ; pages:1848-1851 ; extent:4
Chemistry ; 15, Heft 12 (2020), 1848-1851 (gesamt 4)
- Creator
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Jakob, Christian H. G.
Dominelli, Bruno
Rieb, Julia
Jandl, Christian
Pöthig, Alexander
Reich, Robert M.
Correia, João D. G.
Kühn, Fritz E.
- DOI
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10.1002/asia.202000453
- URN
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urn:nbn:de:101:1-2022061412551743065932
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
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Associated
- Jakob, Christian H. G.
- Dominelli, Bruno
- Rieb, Julia
- Jandl, Christian
- Pöthig, Alexander
- Reich, Robert M.
- Correia, João D. G.
- Kühn, Fritz E.
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