Dinuclear Gold (I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands

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Abstract: A novel N,N’‐allyl‐bridged bisimidazolium salt and a novel dinuclear Ag (I) and a Au (I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl‐group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd (II).

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Dinuclear Gold (I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands ; volume:15 ; number:12 ; year:2020 ; pages:1848-1851 ; extent:4
Chemistry ; 15, Heft 12 (2020), 1848-1851 (gesamt 4)

Urheber
Jakob, Christian H. G.
Dominelli, Bruno
Rieb, Julia
Jandl, Christian
Pöthig, Alexander
Reich, Robert M.
Correia, João D. G.
Kühn, Fritz E.

DOI
10.1002/asia.202000453
URN
urn:nbn:de:101:1-2022061412551743065932
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:23 MESZ

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Beteiligte

  • Jakob, Christian H. G.
  • Dominelli, Bruno
  • Rieb, Julia
  • Jandl, Christian
  • Pöthig, Alexander
  • Reich, Robert M.
  • Correia, João D. G.
  • Kühn, Fritz E.

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