Size‐Selective Binding of Sodium and Potassium Ions in Nanoporous Thin Films of Polymerized Liquid Crystals

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The development of a nanoporous material from a columnar liquid crystalline complex between a polymerizable benzoic acid derivative and a 1,3,5‐tris (1H‐benzo[d]imidazol‐2‐yl) benzene template molecule is described. The morphology of the liquid crystalline complex is retained upon polymerization and quantitative removal of the template molecule affords a nanoporous material with the same lattice parameters. The nanoporous material selectively binds cations from aqueous solution, with selectivity for sodium and potassium ions over lithium and barium ions, as shown with FT‐IR. Binding is also quantified gravimetrically with a quartz crystal microbalance with dissipation monitoring, a technique that is used for this purpose for the first time here.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Size‐Selective Binding of Sodium and Potassium Ions in Nanoporous Thin Films of Polymerized Liquid Crystals ; volume:26 ; number:44 ; year:2016 ; pages:8023-8030 ; extent:8
Advanced functional materials ; 26, Heft 44 (2016), 8023-8030 (gesamt 8)

Creator: Bögels, Gerardus M.
Lugger, Jody A. M.
Goor, Olga J. G. M.
Sijbesma, Rint P.

DOI: 10.1002/adfm.201603408

URN: urn:nbn:de:101:1-2022110907140550497321

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:33 AM CEST

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Bögels, Gerardus M.
Lugger, Jody A. M.
Goor, Olga J. G. M.
Sijbesma, Rint P.

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Size‐Selective Binding of Sodium and Potassium Ions in Nanoporous Thin Films of Polymerized Liquid Crystals

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Other Objects (12)

POTASSIUM-SODIUM

Phase transitions and crystallographic compatibility in ferroelectric bulk and thin film potassium sodium niobate

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Electrosorption mechanisms of bioactive ions in nanoporous carbon materials

Anion Vacancy Regulated Sodium/Potassium Intercalation in Potassium Prussian Blue Analog Cathodes for Hybrid Sodium‐Ion Batteries

Reducing potassium deficiency by using sodium fertilisation

Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries

BODIPY‐Equipped Benzo‐Crown‐Ethers as Fluorescent Sensors for pH Independent Detection of Sodium and Potassium Ions

The Level-Crossing Effect in sodium and potassium

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Ferroelectric domains in potassium sodium niobate thin films: impact of epitaxial strain on thermally induced phase transitions

Magnetic resonance imaging of physiological sodium (23Na) and potassium (39K) ions in human skeletal muscle tissue at 3T and 7T

POTASSIUM-SODIUM

Phase transitions and crystallographic compatibility in ferroelectric bulk and thin film potassium sodium niobate

Protein Does Not Interfere with the lon-Selective Electrode Determination of Calcium, Sodium or Potassium Ions

Electrosorption mechanisms of bioactive ions in nanoporous carbon materials

Anion Vacancy Regulated Sodium/Potassium Intercalation in Potassium Prussian Blue Analog Cathodes for Hybrid Sodium‐Ion Batteries

Reducing potassium deficiency by using sodium fertilisation

Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries

BODIPY‐Equipped Benzo‐Crown‐Ethers as Fluorescent Sensors for pH Independent Detection of Sodium and Potassium Ions

The Level-Crossing Effect in sodium and potassium

Computational Study of Voltage-gated Sodium/Potassium channels

Ferroelectric domains in potassium sodium niobate thin films: impact of epitaxial strain on thermally induced phase transitions

Magnetic resonance imaging of physiological sodium (23Na) and potassium (39K) ions in human skeletal muscle tissue at 3T and 7T

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Ferroelectric domains in potassium sodium niobate thin films: impact of epitaxial strain on thermally induced phase transitions

Magnetic resonance imaging of physiological sodium (23Na) and potassium (39K) ions in human skeletal muscle tissue at 3T and 7T

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