Covalent 2D‐Engineering of Graphene by Spatially Resolved Laser Writing/Reading/Erasing

Abstract: We report a facile and efficient method for the covalent 2D‐patterning of monolayer graphene via laser irradiation. We utilized the photo‐cleavage of dibenzoylperoxide (DBPO) and optimized the subsequent radical additions to non‐activated graphene up to that level where controlled covalent 2D‐patterning of graphene initiated by spatially resolved laser writing is possible. The covalent 2D‐functionalization of graphene, which is monitored by scanning Raman microscopy (SRM) is completely reversible. This new concept enables write/read/erase control over the covalent chemical information stored on the graphene surface.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Covalent 2D‐Engineering of Graphene by Spatially Resolved Laser Writing/Reading/Erasing ; volume:59 ; number:51 ; year:2020 ; pages:23329-23334 ; extent:6
Angewandte Chemie / International edition. International edition ; 59, Heft 51 (2020), 23329-23334 (gesamt 6)

Creator
Edelthalhammer, Konstantin Felix
Dasler, Daniela
Jurkiewicz, Lisa
Nagel, Tamara
Al‐Fogra, Sabrin
Hauke, Frank
Hirsch, Andreas

DOI
10.1002/anie.202006874
URN
urn:nbn:de:101:1-2022061111585902886531
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:31 AM CEST

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Associated

  • Edelthalhammer, Konstantin Felix
  • Dasler, Daniela
  • Jurkiewicz, Lisa
  • Nagel, Tamara
  • Al‐Fogra, Sabrin
  • Hauke, Frank
  • Hirsch, Andreas

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