Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid
Abstract: The accumulation of chiral ammonium‐oxocarbenium dications in superacid is evidenced by low‐temperature NMR spectroscopy, X‐ray diffraction analysis and confirmed by DFT calculations. Its potential for the diastereoselective remote hydrofunctionalization of non‐activated alkene is also explored.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid ; day:25 ; month:04 ; year:2024 ; extent:10
Angewandte Chemie / International edition. International edition ; (25.04.2024) (gesamt 10)
- Creator
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Berrino, Emanuela
Cantin, Thomas
Artault, Maxime
Beck, Stefanie
Jessen, Christoph
Marrot, Jérôme
Guégan, Frédéric
Mingot, Agnès
Kornath, Andreas
Thibaudeau, Sébastien
- DOI
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10.1002/anie.202404066
- URN
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urn:nbn:de:101:1-2404251437347.634798181888
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:46 AM CEST
Data provider
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Associated
- Berrino, Emanuela
- Cantin, Thomas
- Artault, Maxime
- Beck, Stefanie
- Jessen, Christoph
- Marrot, Jérôme
- Guégan, Frédéric
- Mingot, Agnès
- Kornath, Andreas
- Thibaudeau, Sébastien
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Synthesis of [2.2]Paracyclophane‐Based Glycidic Amides Using Chiral Ammonium Ylides
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Long-range current-induced spin accumulation in chiral crystals
Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid
Chiral Ammonium Betaines as Bifunctional Organocatalysts
(Thio) urea containing chiral ammonium salt catalysts
Chiral Quaternary Ammonium Salt‐Catalyzed Enantioselective Addition Reactions of Hydantoins
Chiral ammonium betaine-catalyzed asymmetric Mannich-type reaction of oxindoles
Synthesis and reactivity of Chiral N-Heterocyclic Iodanes
Synthesis of [2.2]Paracyclophane‐Based Glycidic Amides Using Chiral Ammonium Ylides
Identification and characterization of glomeromycotan ammonium transporters
Generation and Reactivity of C(1)‐Ammonium Enolates by Using Isothiourea Catalysis
Dimetalloxycarbene: synthesis, characterization, and reactivity
Chiral gels derived from secondary ammonium salts of (1R,3S)-(+)-camphoric acid
Long-range current-induced spin accumulation in chiral crystals
Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid
Chiral Ammonium Betaines as Bifunctional Organocatalysts
(Thio) urea containing chiral ammonium salt catalysts
Chiral Quaternary Ammonium Salt‐Catalyzed Enantioselective Addition Reactions of Hydantoins
Chiral ammonium betaine-catalyzed asymmetric Mannich-type reaction of oxindoles
Synthesis and reactivity of Chiral N-Heterocyclic Iodanes
Synthesis of [2.2]Paracyclophane‐Based Glycidic Amides Using Chiral Ammonium Ylides
Identification and characterization of glomeromycotan ammonium transporters
Generation and Reactivity of C(1)‐Ammonium Enolates by Using Isothiourea Catalysis
Dimetalloxycarbene: synthesis, characterization, and reactivity
Chiral gels derived from secondary ammonium salts of (1R,3S)-(+)-camphoric acid