Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid
Abstract: The accumulation of chiral ammonium‐oxocarbenium dications in superacid is evidenced by low‐temperature NMR spectroscopy, X‐ray diffraction analysis and confirmed by DFT calculations. Its potential for the diastereoselective remote hydrofunctionalization of non‐activated alkene is also explored.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid ; day:25 ; month:04 ; year:2024 ; extent:10
Angewandte Chemie / International edition. International edition ; (25.04.2024) (gesamt 10)
- Urheber
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Berrino, Emanuela
Cantin, Thomas
Artault, Maxime
Beck, Stefanie
Jessen, Christoph
Marrot, Jérôme
Guégan, Frédéric
Mingot, Agnès
Kornath, Andreas
Thibaudeau, Sébastien
- DOI
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10.1002/anie.202404066
- URN
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urn:nbn:de:101:1-2404251437347.634798181888
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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14.08.2025, 10:46 MESZ
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Beteiligte
- Berrino, Emanuela
- Cantin, Thomas
- Artault, Maxime
- Beck, Stefanie
- Jessen, Christoph
- Marrot, Jérôme
- Guégan, Frédéric
- Mingot, Agnès
- Kornath, Andreas
- Thibaudeau, Sébastien
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