Isolation of Cyclic (Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium (0) Complex

to related objects

Abstract: The long‐sought carbene–bismuthinidene, (CAAC) Bi (Ph), has been synthesized. Notably, this represents both the first example of a carbene‐stabilized subvalent bismuth complex and the extension of the carbene‐pnictinidene concept to a non‐toxic metallic element (Bi). The bonding has been investigated by single‐crystal X‐ray diffraction studies and DFT calculations. This report also highlights the hitherto unknown reducing and ligand transfer capability of a beryllium (0) complex.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Isolation of Cyclic (Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium (0) Complex ; volume:25 ; number:17 ; year:2019 ; pages:4335-4339 ; extent:5
Chemistry - a European journal ; 25, Heft 17 (2019), 4335-4339 (gesamt 5)

Creator
Wang, Guocang
Freeman, Lucas A.
Dickie, Diane
Mokrai, Réka
Benkő, Zoltán
Gilliard, Robert J.

DOI
10.1002/chem.201900458
URN
urn:nbn:de:101:1-2022080407463011045534
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:37 AM CEST

Data provider

This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Show original at data provider

Associated

  • Wang, Guocang
  • Freeman, Lucas A.
  • Dickie, Diane
  • Mokrai, Réka
  • Benkő, Zoltán
  • Gilliard, Robert J.

Other Objects (12)

N‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Adducts of Antimony(III)

N‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Adducts of Antimony(III)

N‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Adducts of Antimony(III)

N‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Adducts of Antimony(III)

Isolation of a New Silepin with an Imine Ligand Based on Cyclic Alkyl Amino Carbene

Isolation of a New Silepin with an Imine Ligand Based on Cyclic Alkyl Amino Carbene

Cyclic Alkyl (amino) Carbene‐Induced Rearrangement of Ga‐Phosphaketene

Cyclic Alkyl (amino) Carbene‐Induced Rearrangement of Ga‐Phosphaketene

Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers

Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers

A Versatile Route To Cyclic (Alkyl)(Amino)Carbene–Stabilized Stibinidenes

A Versatile Route To Cyclic (Alkyl)(Amino)Carbene–Stabilized Stibinidenes

Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers

Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers

A Versatile Route To Cyclic (Alkyl)(Amino) Carbene‐Stabilized Stibinidenes

A Versatile Route To Cyclic (Alkyl)(Amino) Carbene‐Stabilized Stibinidenes

MeCAAC=N-: A Cyclic (Alkyl)(Amino)Carbene Imino Ligand

MeCAAC=N-: A Cyclic (Alkyl)(Amino)Carbene Imino Ligand

N ‐Heterocyclic Carbene and Cyclic (Alkyl)(amino) carbene Complexes of Titanium (IV) and Titanium (III)

N ‐Heterocyclic Carbene and Cyclic (Alkyl)(amino) carbene Complexes of Titanium (IV) and Titanium (III)

N-Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Complexes of Titanium(IV) and Titanium(III)

N-Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Complexes of Titanium(IV) and Titanium(III)

N‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Adducts of Germanium(IV) and Tin(IV) Chlorides and Organyl Chlorides

N‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Adducts of Germanium(IV) and Tin(IV) Chlorides and Organyl Chlorides

Related objects