Isolation of Cyclic (Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium (0) Complex

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Abstract: The long‐sought carbene–bismuthinidene, (CAAC) Bi (Ph), has been synthesized. Notably, this represents both the first example of a carbene‐stabilized subvalent bismuth complex and the extension of the carbene‐pnictinidene concept to a non‐toxic metallic element (Bi). The bonding has been investigated by single‐crystal X‐ray diffraction studies and DFT calculations. This report also highlights the hitherto unknown reducing and ligand transfer capability of a beryllium (0) complex.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Isolation of Cyclic (Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium (0) Complex ; volume:25 ; number:17 ; year:2019 ; pages:4335-4339 ; extent:5
Chemistry - a European journal ; 25, Heft 17 (2019), 4335-4339 (gesamt 5)

Urheber
Wang, Guocang
Freeman, Lucas A.
Dickie, Diane
Mokrai, Réka
Benkő, Zoltán
Gilliard, Robert J.

DOI
10.1002/chem.201900458
URN
urn:nbn:de:101:1-2022080407463011045534
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:37 MESZ

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Beteiligte

  • Wang, Guocang
  • Freeman, Lucas A.
  • Dickie, Diane
  • Mokrai, Réka
  • Benkő, Zoltán
  • Gilliard, Robert J.

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