A Continuous Flow Cell for High‐Temperature/High‐Pressure Electroorganic Synthesis
Abstract: A flow electrolysis cell that enables operation at high temperatures and pressures has been designed and developed. The cell, with a cylindrical shape and concentric electrodes, can be easily assembled using commercially available fluidic components. The compact design of the device permits easy temperature control using a commercial column heater. Temperatures ranging from −10 °C to +150 °C and pressures up to 70 bar have been successfully applied for long operation periods. The cell performance has been evaluated using the anodic methoxylation of N‐formylpiperidine as a model. Very high conversions and selectivities have been achieved with single‐pass processing, and high productivities of 73 mmol/h with electrolyte recycling. The high pressure and temperature capabilities of the cell have been used to demonstrate the negative effect that re‐dissolved hydrogen gas can have on hydrogen‐releasing electrochemical reactions in undivided cells, owing to undesired anodic oxidation of hydrogen.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
A Continuous Flow Cell for High‐Temperature/High‐Pressure Electroorganic Synthesis ; volume:7 ; number:13 ; year:2020 ; pages:2777-2783 ; extent:7
ChemElectroChem ; 7, Heft 13 (2020), 2777-2783 (gesamt 7)
- Creator
- DOI
-
10.1002/celc.202000696
- URN
-
urn:nbn:de:101:1-2022062612045494388326
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:20 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Jud, Wolfgang
- Kappe, Christian Oliver
- Cantillo, David
Other Objects (12)
High pressure study of high-temperature superconductors
Research techniques for high pressure and high temperature
High-pressure high-temperature preparation of CeGe 3
(Ultra) High Pressure Homogenization for Continuous High Pressure Sterilization of Pumpable Foods – A Review
Experimental investigation of high-pressure, high-temperature solid fuel gasification
n-Hexane injection into high-temperature and high-pressure environments
High pressure - high temperature : investigations of solid oxides and fluorides
The 5-th element : a new high pressure high temperature allotrope
High temperature superconductivity in sulfur and selenium hydrides at high pressure
High-pressure high-temperature behavior of polymer derived amorphous B-C-N
High‐pressure and high‐temperature synthesis of crystalline Sb 3 N 5
High‐pressure and high‐temperature synthesis of crystalline Sb 3 N 5
High pressure study of high-temperature superconductors
Research techniques for high pressure and high temperature
High-pressure high-temperature preparation of CeGe 3
(Ultra) High Pressure Homogenization for Continuous High Pressure Sterilization of Pumpable Foods – A Review
Experimental investigation of high-pressure, high-temperature solid fuel gasification
n-Hexane injection into high-temperature and high-pressure environments
High pressure - high temperature : investigations of solid oxides and fluorides
The 5-th element : a new high pressure high temperature allotrope
High temperature superconductivity in sulfur and selenium hydrides at high pressure
High-pressure high-temperature behavior of polymer derived amorphous B-C-N
High‐pressure and high‐temperature synthesis of crystalline Sb 3 N 5
High‐pressure and high‐temperature synthesis of crystalline Sb 3 N 5
High pressure study of high-temperature superconductors
Research techniques for high pressure and high temperature
High-pressure high-temperature preparation of CeGe 3
(Ultra) High Pressure Homogenization for Continuous High Pressure Sterilization of Pumpable Foods – A Review
Experimental investigation of high-pressure, high-temperature solid fuel gasification
n-Hexane injection into high-temperature and high-pressure environments
High pressure - high temperature : investigations of solid oxides and fluorides
The 5-th element : a new high pressure high temperature allotrope
High temperature superconductivity in sulfur and selenium hydrides at high pressure
High-pressure high-temperature behavior of polymer derived amorphous B-C-N
High‐pressure and high‐temperature synthesis of crystalline Sb 3 N 5