Catalytic myrtenol amination over gold, supported on alumina doped with ceria and zirconia
Abstract: In the current work gold catalysts supported on both commercial oxides and oxides synthesized by the sol-gel method were used for the one-pot alcohol amination of myrtenol. In general, utilization of metal oxides synthesized by the sol-gel method as the gold catalyst support enhanced the knowledge regarding key parameters determining catalytic behavior. Synthesized alumina was characterized by stronger acid sites favoring primary amine accumulation on the catalyst surface, as compared to the commercial oxide. Utilization of mixed metal oxides synthesized by the sol-gel method resulted in the non-additive behavior of different oxides enhancing the catalytic activity. Introduction of ceria into alumina modified the support basicity resulting in more efficient alcohol activation.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Catalytic myrtenol amination over gold, supported on alumina doped with ceria and zirconia ; volume:5 ; number:1 ; year:2018 ; pages:49-58 ; extent:10
Catalysis for sustainable energy ; 5, Heft 1 (2018), 49-58 (gesamt 10)
- Creator
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Demidova, Yu.S.
Simakova, I.L.
Suslov, E.V.
Volcho, K.P.
Salakhutdinov, N.F.
Simakov, A.
Murzin, D.Yu.
- DOI
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10.1515/cse-2018-0007
- URN
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urn:nbn:de:101:1-2411121610560.803596051398
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:27 AM CEST
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Associated
- Demidova, Yu.S.
- Simakova, I.L.
- Suslov, E.V.
- Volcho, K.P.
- Salakhutdinov, N.F.
- Simakov, A.
- Murzin, D.Yu.
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Hydrogenations with Hydrotalcite-Supported Gold–Ceria Nanocomposites
Boosting intermediate temperature performance of solid oxide fuel cells via a tri-layer ceria–zirconia–ceria electrolyte
Benzylic C–H Borylation on Ceria-Supported Nickel Hydroxides
Towards Methane Combustion Mechanism on Metal Oxides Supported Catalysts: Ceria Supported Palladium Catalysts
The negative effect of ceria on the propene selectivity for isopropanol decomposition over phosphated and phosphate-free ceria/alumina catalysts
Reductive Amination of Carbonyl Compounds on Nb2O5-Supported Ruthenium
High resolution spectroscopy as a tool to unravel structure-reactivity relationships in Eu3+ doped Ceria/Ceria-Zirconia based catalyst nanomaterials
Properties of 2 mol% yttria stabilized zirconia-alumina-cerium hexaaluminate composites
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Ceria - zirconia thin films : influence of nanostructure and moisture on charge transport properties
Mechanical properties of alumina-zirconia and alumina-zirconia-silicon carbid ceramic composites
Effect of a novel framework design in ceria-stabilized zirconia/alumina nanocomposite (Ce-TZP/A)-based all-ceramic crowns
Hydrogenations with Hydrotalcite-Supported Gold–Ceria Nanocomposites
Boosting intermediate temperature performance of solid oxide fuel cells via a tri-layer ceria–zirconia–ceria electrolyte
Benzylic C–H Borylation on Ceria-Supported Nickel Hydroxides
Towards Methane Combustion Mechanism on Metal Oxides Supported Catalysts: Ceria Supported Palladium Catalysts
The negative effect of ceria on the propene selectivity for isopropanol decomposition over phosphated and phosphate-free ceria/alumina catalysts
Reductive Amination of Carbonyl Compounds on Nb2O5-Supported Ruthenium
High resolution spectroscopy as a tool to unravel structure-reactivity relationships in Eu3+ doped Ceria/Ceria-Zirconia based catalyst nanomaterials
Properties of 2 mol% yttria stabilized zirconia-alumina-cerium hexaaluminate composites
Alumina-doped zirconia submicro-particles : synthesis, thermal stability, and microstructural characterization