The Unusual Mesophases and Properties Exhibited by a Family of Glycosteroids
Abstract: In this article we describe research on the synthesis and characterization of a family of “Janus” amphiphiles composed of disaccharide head groups and alkaloid units joined together via a methylene linker, and bearing a lateral aliphatic chain of varying length. The condensed phases formed by self‐organization of the products as a function of temperature were characterized by differential scanning calorimetry, thermal polarized light microscopy, and small angle X‐ray scattering, allied with computational modelling and simulations. Structural studies on heating specimens from the solid showed that some homologues exhibited lamellar, columnar and bicontinuous mesophases, whereas the same homologues revealed different phase sequences on cooling from the amorphous liquid. We explore these unusual results, which are revealed via supercooling.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
The Unusual Mesophases and Properties Exhibited by a Family of Glycosteroids ; day:31 ; month:01 ; year:2025 ; extent:18
Chemistry - a European journal ; (31.01.2025) (gesamt 18)
- Urheber
-
Ali‐Rachedi, Fahima
Xavier, Nuno M.
Yue, Xiaoyang
Chambert, Stéphane
Liu, Feng
Abbott, Laurence C.
Moore, John N.
Zeng, Xiangbing
Cowling, Stephen J.
Queneau, Yves
Goodby, John W.
- DOI
-
10.1002/chem.202403678
- URN
-
urn:nbn:de:101:1-2502031308308.666881111340
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:24 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Ali‐Rachedi, Fahima
- Xavier, Nuno M.
- Yue, Xiaoyang
- Chambert, Stéphane
- Liu, Feng
- Abbott, Laurence C.
- Moore, John N.
- Zeng, Xiangbing
- Cowling, Stephen J.
- Queneau, Yves
- Goodby, John W.
Ähnliche Objekte (12)
Unusual case of a protruding mass in the esophagus successfully treated by endoscopic submucosal dissection
A note on singular integrals with angular integrability
Closure of a large mucosal defect after endoscopic submucosal dissection using “pre-detached loop and clips” method with a single-channel gastroscope
Endpoint regularity of discrete multisublinear fractional maximal operators associated with ℓ1 $\ell^1}$-balls
Endoscopic treatment of esophageal intramural abscess caused by embedded metal clip: a rare delayed complication of endoscopic submucosal dissection
Regularity for commutators of the local multilinear fractional maximal operators
A rare colonic neoplasm with submucosal bulge successfully treated by endoscopic submucosal dissection
Formulation of scale transformation in a stochastic data assimilation framework
A note on Marcinkiewicz integrals supported by submanifolds
Magneto-optical properties of II-VI semiconductor colloidal nanostructures
Executive turnover in China's state-owned enterprises: Government-oriented or market-oriented?
Successful endoscopic submucosal dissection of a large cavernous hemangioma in the colon
Unusual case of a protruding mass in the esophagus successfully treated by endoscopic submucosal dissection
A note on singular integrals with angular integrability
Closure of a large mucosal defect after endoscopic submucosal dissection using “pre-detached loop and clips” method with a single-channel gastroscope
Endpoint regularity of discrete multisublinear fractional maximal operators associated with ℓ1 $\ell^1}$-balls
Endoscopic treatment of esophageal intramural abscess caused by embedded metal clip: a rare delayed complication of endoscopic submucosal dissection
Regularity for commutators of the local multilinear fractional maximal operators
A rare colonic neoplasm with submucosal bulge successfully treated by endoscopic submucosal dissection
Formulation of scale transformation in a stochastic data assimilation framework
A note on Marcinkiewicz integrals supported by submanifolds
Magneto-optical properties of II-VI semiconductor colloidal nanostructures
Executive turnover in China's state-owned enterprises: Government-oriented or market-oriented?
Successful endoscopic submucosal dissection of a large cavernous hemangioma in the colon
Unusual case of a protruding mass in the esophagus successfully treated by endoscopic submucosal dissection
A note on singular integrals with angular integrability
Closure of a large mucosal defect after endoscopic submucosal dissection using “pre-detached loop and clips” method with a single-channel gastroscope
Endpoint regularity of discrete multisublinear fractional maximal operators associated with ℓ1 $\ell^1}$-balls
Endoscopic treatment of esophageal intramural abscess caused by embedded metal clip: a rare delayed complication of endoscopic submucosal dissection
Regularity for commutators of the local multilinear fractional maximal operators
A rare colonic neoplasm with submucosal bulge successfully treated by endoscopic submucosal dissection
Formulation of scale transformation in a stochastic data assimilation framework
A note on Marcinkiewicz integrals supported by submanifolds
Magneto-optical properties of II-VI semiconductor colloidal nanostructures
Executive turnover in China's state-owned enterprises: Government-oriented or market-oriented?