Milestones in microwave-assisted organophosphorus chemistry

Abstract: Our recent results in the field of microwave (MW)-assisted organophosphorus syntheses, especially regarding esterifications, condensations, substitutions and additions are surveyed. Beside making organic chemical reactions more efficient, it was possible to perform transformations that are reluctant on conventional heating. Another option is to substitute catalysts, or to simplify catalyst systems under MW conditions. It is also the purpose of this paper to elucidate the scope and limitations of the MW tool, to interpret the MW effects, and to model the distribution of the local overheatings and their beneficial effect. All these considerations are possible on the basis of the enthalpy of activations determined by us utilizing the Arrhenius equation and the pseudo first order kinetic equation.

Angaben zum Objekt

• Standort: Deutsche Nationalbibliothek Frankfurt am Main
• Umfang: Online-Ressource
• Sprache: Englisch

Verweise und Beziehungen

• Erschienen in: Milestones in microwave-assisted organophosphorus chemistry ; volume:88 ; number:10-11 ; year:2016 ; pages:931-939 ; extent:9 ; Pure and applied chemistry ; 88, Heft 10-11 (2016), 931-939 (gesamt 9)

Beteiligte, Orts- und Zeitangaben

• Urheber: Keglevich, György ; Kiss, Nóra Zs. ; Mucsi, Zoltán

Weitere Informationen

• DOI: 10.1515/pac-2016-0604
• URN: urn:nbn:de:101:1-2024030613261395440989
• Rechteinformation: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Letzte Aktualisierung: 14.08.2025, 10:57 MESZ