Electrochemical behavior of some purine derivatives on carbon based electrodes

Abstract: The electrochemical behaviour of three purine derivatives was investigated by cyclic voltammetry on different electrode materials: glassy carbon in native form and electrochemically activated, carbon paste electrode unmodified or modified with 1, 4-benzoquinone. The preliminary study obtained on solid electrodes was extended to graphite based planar screen-printed electrodes, unmodified and modified with multi-wall carbon nanotubes, or cobalt phthalocyanine. The influence of some experimental parameters (pH, scan rate, concentration and electrolytic medium) on the electrochemical behaviour of these alkaloids was also examined. The electrochemical oxidation of purine derivatives is an irreversible and diffusion controlled process, proved by the linear dependence between the peak potentials and the logarithm of scan rates and between the anodic peak current and the square root of scan rate.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Electrochemical behavior of some purine derivatives on carbon based electrodes ; volume:9 ; number:3 ; year:2011 ; pages:466-473 ; extent:8
Open chemistry ; 9, Heft 3 (2011), 466-473 (gesamt 8)

Creator
Câmpean, Anuţa
Tertiş, Mihaela
Săndulescu, Robert

DOI
10.2478/s11532-011-0026-6
URN
urn:nbn:de:101:1-2410181659381.781862287127
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:28 AM CEST

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Associated

  • Câmpean, Anuţa
  • Tertiş, Mihaela
  • Săndulescu, Robert

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