Fully Bridged Triphenylamines Comprising Five‐ and Seven‐Membered Rings
Abstract: A family of fully bridged triphenylamines with embedded 5‐ and 7‐membered rings is presented. The compounds are potent electron donors capable to undergo donor/acceptor interactions with strong cyano‐based acceptors both in the solid state and solution. These interactions were evaluated by IR and UV/vis spectroscopy as well as X‐ray crystallography. The vinylene‐bridged compound was oxidized to the corresponding 1,2‐diketone which readily underwent acid‐catalyzed condensation with selected 1,2‐phenylenediamines. The resulting π‐extended quinoxaline derivatives represent valuable building blocks for the development of functional chromophores upon appropriate functionalization.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Fully Bridged Triphenylamines Comprising Five‐ and Seven‐Membered Rings ; day:09 ; month:05 ; year:2022 ; extent:1
Chemistry - a European journal ; (09.05.2022) (gesamt 1)
- Urheber
-
Michalsky, Ina
Gensch, Viktoria
Walla, Christian
Hoffmann, Marvin
Rominger, Frank
Oeser, Thomas
Tegeder, Petra
Dreuw, Andreas
Kivala, Milan
- DOI
-
10.1002/chem.202200326
- URN
-
urn:nbn:de:101:1-2022050915115334214829
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:34 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Michalsky, Ina
- Gensch, Viktoria
- Walla, Christian
- Hoffmann, Marvin
- Rominger, Frank
- Oeser, Thomas
- Tegeder, Petra
- Dreuw, Andreas
- Kivala, Milan
Ähnliche Objekte (12)
Fully Bridged Triphenylamines Comprising Five‐ and Seven‐Membered Rings
Ungewöhnliche durch Elektrostatik und Spin stabilisierte anionische Systeme
Optical properties of tolane and tolanophanes : an analysis using the ADC scheme for excited states and spin-orbit coupling elements
Development of a modular quantum-chemistry framework for the investigation of novel basis functions
Quantum Chemical Study of Excited State Proton Transfer in Solvated Organic Molecules
Superlinear Parallel Scaling of Quadrature Evaluated Second-Order Møller-Plesset Perturbation Theory
Development and Application of Quantum Chemical Methods for the Description of Molecules Under Mechanical Stress
Development of Frozen-Density Embedded Algebraic Diagrammatic Construction Schemes for Excited States and Quantum-Chemical Investigation of Photophysical Properties of Tetrathiaheterohelicenes
Quantum Chemical Study of Coupled Molecular Photoswitches
Development of Quantum Chemical Methods for Excited-State and Response properties
Development and Application of Hermitian Methods for Molecular Properties and Excited Electronic States
Development and Implementation of Theoretical Methods for the Description of Electronically Core-Excited States
Fully Bridged Triphenylamines Comprising Five‐ and Seven‐Membered Rings
Ungewöhnliche durch Elektrostatik und Spin stabilisierte anionische Systeme
Optical properties of tolane and tolanophanes : an analysis using the ADC scheme for excited states and spin-orbit coupling elements
Development of a modular quantum-chemistry framework for the investigation of novel basis functions
Quantum Chemical Study of Excited State Proton Transfer in Solvated Organic Molecules
Superlinear Parallel Scaling of Quadrature Evaluated Second-Order Møller-Plesset Perturbation Theory
Development and Application of Quantum Chemical Methods for the Description of Molecules Under Mechanical Stress
Development of Frozen-Density Embedded Algebraic Diagrammatic Construction Schemes for Excited States and Quantum-Chemical Investigation of Photophysical Properties of Tetrathiaheterohelicenes
Quantum Chemical Study of Coupled Molecular Photoswitches
Development of Quantum Chemical Methods for Excited-State and Response properties
Development and Application of Hermitian Methods for Molecular Properties and Excited Electronic States
Development and Implementation of Theoretical Methods for the Description of Electronically Core-Excited States
Fully Bridged Triphenylamines Comprising Five‐ and Seven‐Membered Rings
Ungewöhnliche durch Elektrostatik und Spin stabilisierte anionische Systeme
Optical properties of tolane and tolanophanes : an analysis using the ADC scheme for excited states and spin-orbit coupling elements
Development of a modular quantum-chemistry framework for the investigation of novel basis functions
Quantum Chemical Study of Excited State Proton Transfer in Solvated Organic Molecules
Superlinear Parallel Scaling of Quadrature Evaluated Second-Order Møller-Plesset Perturbation Theory
Development and Application of Quantum Chemical Methods for the Description of Molecules Under Mechanical Stress
Development of Frozen-Density Embedded Algebraic Diagrammatic Construction Schemes for Excited States and Quantum-Chemical Investigation of Photophysical Properties of Tetrathiaheterohelicenes
Quantum Chemical Study of Coupled Molecular Photoswitches
Development of Quantum Chemical Methods for Excited-State and Response properties
Development and Application of Hermitian Methods for Molecular Properties and Excited Electronic States