Light‐Driven Enzymatic Decarboxylation of Fatty Acids
Abstract: The photoenzymatic decarboxylation of fatty acids to alkanes is proposed as an alternative approach for the synthesis of biodiesel. By using a recently discovered photodecarboxylase from Chlorella variabilis NC64A (CvFAP) we demonstrate the irreversible preparation of alkanes from fatty acids and triglycerides. Several fatty acids and their triglycerides are converted by CvFAP in near‐quantitative yield and exclusive selectivity upon illumination with blue light. Very promising turnover numbers of up to 8000 were achieved in this proof‐of‐concept study.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Light‐Driven Enzymatic Decarboxylation of Fatty Acids ; volume:57 ; number:41 ; year:2018 ; pages:13648-13651 ; extent:4
Angewandte Chemie / International edition. International edition ; 57, Heft 41 (2018), 13648-13651 (gesamt 4)
- Urheber
- DOI
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10.1002/anie.201807119
- URN
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urn:nbn:de:101:1-2022082308474944874118
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:30 MESZ
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Beteiligte
- Huijbers, Mieke M. E.
- Zhang, Wuyuan
- Tonin, Fabio
- Hollmann, Frank
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