Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes

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Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: In: Chemistry – A European Journal (25:63) - Weinheim : Wiley - S. 14304-14307

Event: Veröffentlichung

(where): Berlin

(who): Technische Universität Berlin

(when): 2020

Creator: Zhang, Liangliang
Oestreich, Martin

DOI: 10.14279/depositonce-9654

Handle: 11303/10759

URN: urn:nbn:de:101:1-2020021901063317348802

Rights: Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 14.08.2025, 10:54 AM CEST

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Associated

Zhang, Liangliang
Oestreich, Martin
Technische Universität Berlin

Time of origin

2020

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Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes

Transfer hydrosilylation

Asymmetric Synthesis - The Essentials

Transferhydrosilylierung

Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones

B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes

Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen

Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes

Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride

Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes

Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes

Transfer hydrosilylation

Asymmetric Synthesis - The Essentials

Transferhydrosilylierung

Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones

B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes

Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen

Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes

Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride

Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes

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Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes

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Other Objects (12)

Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes

Transfer hydrosilylation

Asymmetric Synthesis - The Essentials

Transferhydrosilylierung

Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones

B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes

Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen

Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes

Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride

Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes

Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes

Transfer hydrosilylation

Asymmetric Synthesis - The Essentials

Transferhydrosilylierung

Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones

B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes

Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen

Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes

Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride

Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes

Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes

Transfer hydrosilylation

Asymmetric Synthesis - The Essentials

Transferhydrosilylierung

Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones

B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes

Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen

Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes

Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride

Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes

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