Rhodium-catalyzed regioselective addition of thioacids to terminal allenes: enantioselective access to branched allylic thioesters
Abstract: Rhodium-catalyzed regio- and enantioselective hydrothiolation of terminal allenes with thioacids is reported for the atom-economic synthesis of chiral branched allylic thioesters. By using a rhodium(I) catalyst system, diversities of terminal allenes and thioacids afforded the corresponding branched thioesters in excellent regioselectivity, high yield, and good enantioselectivity. This method was also explored for Fmoc-protected aminothioacids for diastereoselective synthesis of the corresponding thioesters
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Anmerkungen
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Chemical communications. - 58, 11 (2022) , 1704-1707, ISSN: 1364-548X
- Ereignis
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Veröffentlichung
- (wo)
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Freiburg
- (wer)
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Universität
- (wann)
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2022
- Urheber
- Beteiligte Personen und Organisationen
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Institut für Organische Chemie, Research Group of Prof. Dr. B. Breit
- DOI
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10.1039/D1CC06470C
- URN
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urn:nbn:de:bsz:25-freidok-2253825
- Rechteinformation
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Kein Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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25.03.2025, 13:56 MEZ
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Beteiligte
- Ziyaei Halimehjani, Azim
- Breit, Bernhard
- Institut für Organische Chemie, Research Group of Prof. Dr. B. Breit
- Universität
Entstanden
- 2022
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