Boron‐Locked Starazine – A Soluble and Fluorescent Analogue of Starphene
Abstract: A starlike heterocyclic molecule containing an electron‐deficient nonaaza‐core structure and three peripheral isoquinolines locked by three tetracoordinate borons, namely isoquinoline‐nona‐starazine (QNSA), is synthesized by using readily available reactants through a rather straightforward approach. This new heteroatom‐rich QNSA possesses a quasi‐planar π‐backbone structure, and bears phenyl substituents on borons which protrude on both sides of the π‐backbones endowing it with good solubility in common organic solvents. Contrasting to its starphene analogue, QNSA shows intense fluorescence with a quantum yield (PLQY) of up to 62 % in dilute solution.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Boron‐Locked Starazine – A Soluble and Fluorescent Analogue of Starphene ; day:07 ; month:04 ; year:2022 ; extent:1
Chemistry - a European journal ; (07.04.2022) (gesamt 1)
- Creator
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Feng, Yi
Zhou, Jiadong
Qiu, Honglin
Schnitzlein, Matthias
Hu, Jingtao
Liu, Linlin
Würthner, Frank
Xie, Zengqi
- DOI
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10.1002/chem.202200770
- URN
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urn:nbn:de:101:1-2022040715291780535185
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:36 AM CEST
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Associated
- Feng, Yi
- Zhou, Jiadong
- Qiu, Honglin
- Schnitzlein, Matthias
- Hu, Jingtao
- Liu, Linlin
- Würthner, Frank
- Xie, Zengqi
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