Aerobic Photooxidation of Toluene Derivatives into Carboxylic Acids with Bromine–Water under Catalyst-Free Conditions
The photoirradiation of toluene derivatives with two equivalents of bromine in benzotrifluoride–water provided a satisfactory yield of the corresponding benzoic acid derivatives. Either a fluorescent lamp, blue LED (454 nm), or UV LED (385 nm) was used for the photoreaction. The reaction pathway might proceed through the dibromination of benzylic carbon, generation of the benzylic radical via oxidative C–H abstraction, formation of benzoyl bromide, and hydrolysis of carboxylic acid.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Aerobic Photooxidation of Toluene Derivatives into Carboxylic Acids with Bromine–Water under Catalyst-Free Conditions ; volume:33 ; number:16 ; year:2022 ; pages:1670-1674
Synlett ; 33, Heft 16 (2022), 1670-1674
- Contributor
-
Kirihara, Masayuki
Sakamoto, Yugo
Yamahara, Sho
Kitajima, Atsuhito
Kugisaki, Naoki
Kimura, Yoshikazu
- DOI
-
10.1055/a-1887-7885
- URN
-
urn:nbn:de:101:1-2022112411520314819993
- Rights
-
Kein Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:35 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Kirihara, Masayuki
- Sakamoto, Yugo
- Yamahara, Sho
- Kitajima, Atsuhito
- Kugisaki, Naoki
- Kimura, Yoshikazu
Other Objects (12)
Catalyst-free selective oxidation of C(sp3)-H bonds in toluene on water
Modelling of the photooxidation of toluene: conceptual ideas for validating detailed mechanisms
High formation of secondary organic aerosol from the photo-oxidation of toluene
Secondary organic aerosol formation from toluene photooxidation under various NO x conditions and particle acidity
Wavelength and NO x dependent complex refractive index of SOAs generated from the photooxidation of toluene
Catalyst-free organic synthesis
Photooxidation von Rubren
Real refractive indices and volatility of secondary organic aerosol generated from photooxidation and ozonolysis of limonene, α-pinene and toluene
Ultrastrong catalyst-free polycrystalline diamond
Sul Toluene Bromurato
Aqueous Zinc‐Bromine Battery with Highly Reversible Bromine Conversion Chemistry
Aqueous Zinc‐Bromine Battery with Highly Reversible Bromine Conversion Chemistry
Catalyst-free selective oxidation of C(sp3)-H bonds in toluene on water
Modelling of the photooxidation of toluene: conceptual ideas for validating detailed mechanisms
High formation of secondary organic aerosol from the photo-oxidation of toluene
Secondary organic aerosol formation from toluene photooxidation under various NO x conditions and particle acidity
Wavelength and NO x dependent complex refractive index of SOAs generated from the photooxidation of toluene
Catalyst-free organic synthesis
Photooxidation von Rubren
Real refractive indices and volatility of secondary organic aerosol generated from photooxidation and ozonolysis of limonene, α-pinene and toluene
Ultrastrong catalyst-free polycrystalline diamond
Sul Toluene Bromurato
Aqueous Zinc‐Bromine Battery with Highly Reversible Bromine Conversion Chemistry
Aqueous Zinc‐Bromine Battery with Highly Reversible Bromine Conversion Chemistry
Catalyst-free selective oxidation of C(sp3)-H bonds in toluene on water
Modelling of the photooxidation of toluene: conceptual ideas for validating detailed mechanisms
High formation of secondary organic aerosol from the photo-oxidation of toluene
Secondary organic aerosol formation from toluene photooxidation under various NO x conditions and particle acidity
Wavelength and NO x dependent complex refractive index of SOAs generated from the photooxidation of toluene
Catalyst-free organic synthesis
Photooxidation von Rubren
Real refractive indices and volatility of secondary organic aerosol generated from photooxidation and ozonolysis of limonene, α-pinene and toluene
Ultrastrong catalyst-free polycrystalline diamond
Sul Toluene Bromurato
Aqueous Zinc‐Bromine Battery with Highly Reversible Bromine Conversion Chemistry