Formal Radical Deoxyfluorination of Oxalate‐Activated Alcohols Triggered by the Selectfluor‐DMAP Charge‐Transfer Complex
Abstract: We present a photon‐ and metal‐free approach for the radical fluorination of aliphatic oxalate‐activated alcohols. The method relies on the spontaneous generation of the N‐(chloromethyl) triethylenediamine radical dication, a potent single electron oxidant, from Selectfluor and 4‐(dimethylamino) pyridine. The protocol is easily scalable and provides the desired fluorinated products within only a few minutes reaction time.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Formal Radical Deoxyfluorination of Oxalate‐Activated Alcohols Triggered by the Selectfluor‐DMAP Charge‐Transfer Complex ; day:28 ; month:09 ; year:2023 ; extent:5
European journal of organic chemistry ; (28.09.2023) (gesamt 5)
- Urheber
- DOI
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10.1002/ejoc.202300769
- URN
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urn:nbn:de:101:1-2023092815162611299487
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 14.08.2025, 10:47 MESZ
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Beteiligte
- Baunis, Haralds
- Pieber, Bartholomäus
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