Regiospecific N‐Arylation of Aliphatic Amines under Mild and Metal‐Free Reaction Conditions
Abstract: A transition metal‐free N‐arylation of primary and secondary amines with diaryliodonium salts is presented. Both acyclic and cyclic amines are well tolerated, providing a large set of N‐alkyl anilines. The methodology is unprecedented among metal‐free methods in terms of amine scope, the ability to transfer both electron‐withdrawing and electron‐donating aryl groups, and efficient use of resources, as excess substrate or reagents are not required.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Regiospecific N‐Arylation of Aliphatic Amines under Mild and Metal‐Free Reaction Conditions ; volume:130 ; number:35 ; year:2018 ; pages:11597-11601 ; extent:5
Angewandte Chemie ; 130, Heft 35 (2018), 11597-11601 (gesamt 5)
- Urheber
- DOI
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10.1002/ange.201807001
- URN
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urn:nbn:de:101:1-2022082005584894916383
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:37 MESZ
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Beteiligte
- Purkait, Nibadita
- Kervefors, Gabriella
- Linde, Erika
- Olofsson, Berit
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