A Modular Synthesis of Substituted Cycloparaphenylenes
Abstract: Herein, we report a modular synthesis providing access to substituted cycloparaphenylenes (CPPs) of different sizes. A key synthon introducing two geminal ester units was efficiently prepared by [2+2+2] cycloaddition. This building block can be conveniently converted to macrocyclic precursors controlling the ring size of the final CPP. Efficient reductive aromatization through single‐electron transfer provided the substituted nanohoops in a straightforward manner. The tBu ester substitution pattern enables a tube‐like arrangement in the solid‐state governed by van der Waals interactions that exhibits one of the tightest packings of CPPs in tube direction, thus opening new avenues in the crystal design of CPPs.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
A Modular Synthesis of Substituted Cycloparaphenylenes ; day:27 ; month:01 ; year:2022 ; extent:1
Chemistry - a European journal ; (27.01.2022) (gesamt 1)
- Creator
- DOI
-
10.1002/chem.202104239
- URN
-
urn:nbn:de:101:1-2022012714312159234274
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:33 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Kohs, Daniel
- Becker, Jonathan
- Wegner, Hermann A.
Other Objects (12)
Synthesis of Substituted Iptycenes
Synthesis of Substituted 2-Aminoimidazoles
Mechanochemical Synthesis of Pyrrole-Substituted Polyynes
Selective synthesis of α-substituted oligothiophenes
Simple Synthesis of Substituted Polyheteroaromatic Compounds
Iridium-Catalyzed Synthesis of Substituted Piperazines
Stereocontrolled Synthesis of Highly Substituted Tetrahydropyrans
Compositional synthesis of modular systems
Substituted Dihydropyridine Synthesis by Dearomatization of Pyridines
Cobalt-mediated regioselective synthesis of substituted tetrahydroquinolines
Synthesis and biological profile of substituted benzimidazoles
One-Pot Synthesis of α-Substituted Acrylates
Synthesis of Substituted Iptycenes
Synthesis of Substituted 2-Aminoimidazoles
Mechanochemical Synthesis of Pyrrole-Substituted Polyynes
Selective synthesis of α-substituted oligothiophenes
Simple Synthesis of Substituted Polyheteroaromatic Compounds
Iridium-Catalyzed Synthesis of Substituted Piperazines
Stereocontrolled Synthesis of Highly Substituted Tetrahydropyrans
Compositional synthesis of modular systems
Substituted Dihydropyridine Synthesis by Dearomatization of Pyridines
Cobalt-mediated regioselective synthesis of substituted tetrahydroquinolines
Synthesis and biological profile of substituted benzimidazoles
One-Pot Synthesis of α-Substituted Acrylates
Synthesis of Substituted Iptycenes
Synthesis of Substituted 2-Aminoimidazoles
Mechanochemical Synthesis of Pyrrole-Substituted Polyynes
Selective synthesis of α-substituted oligothiophenes
Simple Synthesis of Substituted Polyheteroaromatic Compounds
Iridium-Catalyzed Synthesis of Substituted Piperazines
Stereocontrolled Synthesis of Highly Substituted Tetrahydropyrans
Compositional synthesis of modular systems
Substituted Dihydropyridine Synthesis by Dearomatization of Pyridines
Cobalt-mediated regioselective synthesis of substituted tetrahydroquinolines
Synthesis and biological profile of substituted benzimidazoles