Expansion and Compression of a Helicate with Central Diol-Units as Stereocontrolling Moieties

The dicatechol ester ligand 2-H4 forms the compressed helicate Li4[(2) 3Ti2] which upon removal of the internally bound lithium cations expands. In the compressed form, the chiral diol units control the stereochemistry of the complex which is lost upon expansion of the system.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Expansion and Compression of a Helicate with Central Diol-Units as Stereocontrolling Moieties ; day:15 ; month:09 ; year:2022
Organic materials ; (15.09.2022)

Contributor
Grüninger, Saskia
Mevissen, Christian
Ward, Jas S.
Rissanen, Kari
Albrecht, Markus

DOI
10.1055/a-1945-0582
URN
urn:nbn:de:101:1-2022112411294773156323
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:25 AM CEST

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