Palladium‐Catalyzed Carbonylation of Allylic Chlorides to β,γ‐Unsaturated Esters/Amides under Mild Conditions
Abstract: Improved procedures for carbonylative transformations (alkoxy‐ and aminocarbonylation) of cinnamyl chloride to synthesize β,γ‐unsaturated esters/amides have been developed. Studying critical reaction parameters (palladium precursors, solvents and bases) enabled the practical preparation of diverse β,γ‐unsaturated esters/amides under mild conditions (low Pd catalyst loading, phosphine‐free, 2 bar CO, 60 °C). The optimal catalytic system shows excellent chemo‐ and regioselectivity for the activation of the allylic C−Cl bonds.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Palladium‐Catalyzed Carbonylation of Allylic Chlorides to β,γ‐Unsaturated Esters/Amides under Mild Conditions ; volume:2022 ; number:30 ; year:2022 ; extent:5
European journal of organic chemistry ; 2022, Heft 30 (2022) (gesamt 5)
- Urheber
- DOI
-
10.1002/ejoc.202200663
- URN
-
urn:nbn:de:101:1-2022080915072820751091
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:25 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Wang, Peng
- Cao, Zhusong ..
- Wang, Yaxin X.
- Neumann, Helfried
- Beller, Matthias
Ähnliche Objekte (12)
Palladium-catalyzed enantioselective carbonylation reactions
Enantioselective Palladium-Catalyzed Allylic Dearomatization
Palladium-catalyzed carbonylation reactions of aryl halides
Palladium-catalyzed carbonylation of unsaturated carbon-carbon bonds
Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols
Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols
The Heck Carbonylation: Palladium-Catalyzed Alkoxycarbonylation of Organic Halides
Palladium‐Catalyzed Carbonylation in the Synthesis of N‐Ynonylsulfoximines
Palladium-Catalyzed Cross-Couplings of Alkyllithiums with Aryl Chlorides
Palladium-Catalyzed Synthesis of Isatins from Anilines by Double Carbonylation
Making Acid Chlorides from Olefins by Palladium-Catalyzed Regiodivergent Hydrochlorocarbonylation
Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction
Palladium-catalyzed enantioselective carbonylation reactions
Enantioselective Palladium-Catalyzed Allylic Dearomatization
Palladium-catalyzed carbonylation reactions of aryl halides
Palladium-catalyzed carbonylation of unsaturated carbon-carbon bonds
Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols
Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols
The Heck Carbonylation: Palladium-Catalyzed Alkoxycarbonylation of Organic Halides
Palladium‐Catalyzed Carbonylation in the Synthesis of N‐Ynonylsulfoximines
Palladium-Catalyzed Cross-Couplings of Alkyllithiums with Aryl Chlorides
Palladium-Catalyzed Synthesis of Isatins from Anilines by Double Carbonylation
Making Acid Chlorides from Olefins by Palladium-Catalyzed Regiodivergent Hydrochlorocarbonylation
Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction
Palladium-catalyzed enantioselective carbonylation reactions
Enantioselective Palladium-Catalyzed Allylic Dearomatization
Palladium-catalyzed carbonylation reactions of aryl halides
Palladium-catalyzed carbonylation of unsaturated carbon-carbon bonds
Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols
Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols
The Heck Carbonylation: Palladium-Catalyzed Alkoxycarbonylation of Organic Halides
Palladium‐Catalyzed Carbonylation in the Synthesis of N‐Ynonylsulfoximines
Palladium-Catalyzed Cross-Couplings of Alkyllithiums with Aryl Chlorides
Palladium-Catalyzed Synthesis of Isatins from Anilines by Double Carbonylation
Making Acid Chlorides from Olefins by Palladium-Catalyzed Regiodivergent Hydrochlorocarbonylation