Stabilizing Copper (I) Complexes by Terminal Olefinic Side Arms and Studying Their Reactivity Towards Oxidation
Abstract: Many copper (I) complexes with aliphatic amine ligands have a strong tendency to disproportionate to copper (II) and elemental copper in solution at higher concentrations, making it difficult to isolate them and to study their reactivity. A series of copper (I) complexes with ligands based on tridentate N,N,N’,N’’,N’’‐pentamethldiethylenetriamine (Me5dien) were synthesized that included terminal olefinic and aromatic groups. It could be shown that the olefinic side arms stabilized some of the copper (I) complexes. Whether and how strongly the complexes were stabilized depended on the position and length of the olefinic sidearm. Additionally, the reactivity of the copper (I) complexes towards dioxygen was investigated.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Stabilizing Copper (I) Complexes by Terminal Olefinic Side Arms and Studying Their Reactivity Towards Oxidation ; day:07 ; month:11 ; year:2024 ; extent:10
European journal of inorganic chemistry ; (07.11.2024) (gesamt 10)
- Creator
-
Granichny, Alexander
Würtele, Christian
Schindler, Siegfried
- DOI
-
10.1002/ejic.202400570
- URN
-
urn:nbn:de:101:1-2411081407316.755854207498
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:31 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Granichny, Alexander
- Würtele, Christian
- Schindler, Siegfried
Other Objects (12)
Terminal Copper Nitrenoid Formation and Reactivity Induced by Absorption to an Antenna Ligand
Terminal Copper Nitrenoid Formation and Reactivity Induced by Absorption to an Antenna Ligand
Performance of NMPC Schemes without Stabilizing Terminal Constraints
A Distributed NMPC Scheme without Stabilizing Terminal Constraints
Reactivity Trends with Borylalkyl Copper(I) Species
Stability and feasibility of state constrained MPC without stabilizing terminal constraints
Synthesis, characterization and reactivity of copper cluster complexes
Nucleophilic reactivity of a copper(II)-hydroperoxo complex
Synthesis, characterization and reactivity of Copper Cluster Complexes
Stability and feasibility of state-constrained linear MPC without stabilizing terminal constraints
Cooperativity‐Driven Reactivity of a Dinuclear Copper Dimethylglyoxime Complex
Ubiquitin carboxyl-terminal hydrolase 11 promotes autophagy by de-ubiquitinating and stabilizing Beclin-1
Terminal Copper Nitrenoid Formation and Reactivity Induced by Absorption to an Antenna Ligand
Terminal Copper Nitrenoid Formation and Reactivity Induced by Absorption to an Antenna Ligand
Performance of NMPC Schemes without Stabilizing Terminal Constraints
A Distributed NMPC Scheme without Stabilizing Terminal Constraints
Reactivity Trends with Borylalkyl Copper(I) Species
Stability and feasibility of state constrained MPC without stabilizing terminal constraints
Synthesis, characterization and reactivity of copper cluster complexes
Nucleophilic reactivity of a copper(II)-hydroperoxo complex
Synthesis, characterization and reactivity of Copper Cluster Complexes
Stability and feasibility of state-constrained linear MPC without stabilizing terminal constraints
Cooperativity‐Driven Reactivity of a Dinuclear Copper Dimethylglyoxime Complex
Ubiquitin carboxyl-terminal hydrolase 11 promotes autophagy by de-ubiquitinating and stabilizing Beclin-1
Terminal Copper Nitrenoid Formation and Reactivity Induced by Absorption to an Antenna Ligand
Terminal Copper Nitrenoid Formation and Reactivity Induced by Absorption to an Antenna Ligand
Performance of NMPC Schemes without Stabilizing Terminal Constraints
A Distributed NMPC Scheme without Stabilizing Terminal Constraints
Reactivity Trends with Borylalkyl Copper(I) Species
Stability and feasibility of state constrained MPC without stabilizing terminal constraints
Synthesis, characterization and reactivity of copper cluster complexes
Nucleophilic reactivity of a copper(II)-hydroperoxo complex
Synthesis, characterization and reactivity of Copper Cluster Complexes
Stability and feasibility of state-constrained linear MPC without stabilizing terminal constraints
Cooperativity‐Driven Reactivity of a Dinuclear Copper Dimethylglyoxime Complex