Video documented upscaled synthesis of salts of the parent carbaborate ion [CB11H12]-, its undecafluorinated form [CHB11F11]- and useful starting materials for its introduction
Abstract: In this work, we present our improved protocols for the single batch syntheses of approximately 32 g of [NHMe3][CB11H12] and 10 g of Na[CHB11F11] as well as salt metathesis reactions, granting access to useful starting materials to introduce the [CHB11F11]− anion. This includes the trityl cation [Ph3C]+ and the bis-1,2-difluorobenzene-silver(I)-complex [Ag(odfb)2]+, as well as some applications of the shown compounds. The described methodology allows the synthesis of large amounts of both the [CB11H12]− and the [CHB11F11]− anion and therefore making them accessible for further reactions. To facilitate the reproducibility, we present video tutorials of the synthetic steps towards Na[CHB11F11]
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Anmerkungen
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Chemistry methods. - 4, 11 (2024) , e202400011, ISSN: 2628-9725
- Ereignis
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Veröffentlichung
- (wo)
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Freiburg
- (wer)
-
Universität
- (wann)
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2025
- Urheber
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Kulenkampff, Jan
Armbruster, Christian
Drolshagen, Johanna
Regnat, Celine
Wienold, Tina
Spari, Luisa
Fix, Jana M.
Sterbak, Tabea
Scherer, Harald
Krossing, Ingo
- DOI
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10.1002/cmtd.202400011
- URN
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urn:nbn:de:bsz:25-freidok-2620632
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 15.08.2025, 07:24 MESZ
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Beteiligte
- Kulenkampff, Jan
- Armbruster, Christian
- Drolshagen, Johanna
- Regnat, Celine
- Wienold, Tina
- Spari, Luisa
- Fix, Jana M.
- Sterbak, Tabea
- Scherer, Harald
- Krossing, Ingo
- Universität
Entstanden
- 2025
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