α‐Fluorotricarbonyl Derivatives as Versatile Fluorinated Building Blocks: Synthesis of Fluoroacetophenone, Fluoroketo Ester and Fluoropyran‐4‐one Derivatives

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Fluorinated acyl‐Meldrum's acid derivatives were synthesized by electrophilic fluorination of appropriate phenacyl Meldrum's acid substrates using Selectfluor. Reactions with water, ethanol, Grignard, and alkynyllithium reagents gave rise to the corresponding fluoro‐acetophenone, –1,3‐keto ester, –1,3‐diketone and ‐pyran‐4‐one products respectively from the same selectively fluorinated scaffold in one‐step procedures.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: α‐Fluorotricarbonyl Derivatives as Versatile Fluorinated Building Blocks: Synthesis of Fluoroacetophenone, Fluoroketo Ester and Fluoropyran‐4‐one Derivatives ; volume:2020 ; number:25 ; year:2020 ; pages:3872-3878 ; extent:7
European journal of organic chemistry ; 2020, Heft 25 (2020), 3872-3878 (gesamt 7)

Creator: Harsanyi, Antal
Lückener, Anne
Pasztor, Hedvig
Yilmaz, Zahide
Tam, Lawrence
Yufit, Dmitry S.
Sandford, Graham

DOI: 10.1002/ejoc.202000503

URN: urn:nbn:de:101:1-2022070613594307720584

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:20 AM CEST

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Harsanyi, Antal
Lückener, Anne
Pasztor, Hedvig
Yilmaz, Zahide
Tam, Lawrence
Yufit, Dmitry S.
Sandford, Graham

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α‐Fluorotricarbonyl Derivatives as Versatile Fluorinated Building Blocks: Synthesis of Fluoroacetophenone, Fluoroketo Ester and Fluoropyran‐4‐one Derivatives

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